Abstract:
We show that there are two regimes of irreversible, kinetic aggregation of aqueous colloids, determined by the short-range interparticle potential, through its control of the sticking probability upon approach of two particles. Each regime has different rate-limiting physics, aggregation dynamics, and cluster-mass distributions, and results in clusters with different fractal dimensions. These results set limits on the fractal dimension, df, for gold aggregates of 1.75<~df<~2.05(±0.05).
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